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Mix broth, cornmeal, cumin, oregano, cinnamon, salt, chipotle, and garlic in bottom of slow cooker.
Trim fat off of brisket. Sprinkle with chili powder on both sides. Place in slow cooker and turn to coat.
Cover and cook on high 3 hours.
Add potatoes and cook until tender, 1-2 more hours.
Remove meat and potatoes from cooker. Skim fat from sauce. Slice meat and return with potatoes to the sauce. Cover and keep warm until ready to serve.
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